After a slow start to the first set, the former world number one Murray found his form and cruised through his opening match, beating Rubin 6-2, 6-0 in just 58 minutes
In the bearpit atmosphere of Kyrgios's favourite John Cain Arena, US Open champion Thiem dragged himself off the canvas in a thrilling 4-6 4-6 6-3 6-4 6-4 win over the Australian showman to reach the fourth round.
The Austrian third seed was shellshocked for the first two sets, barely able to lay a glove on Kyrgios, who channelled the crowd's energy to produce some electrifying tennis.
Along the way, Kyrgios smashed a racquet, delivered underarm serves, played 'tweener' shots through his own legs, ranted at the umpire and saved two match points.
The volatile Australian rarely sticks around for the second week of his home major but his early round matches on his favourite court are guaranteed entertainment.
Despite the restricted crowds and disappointing turnout over the first three days of a Grand Slam defined by the COVID-19 pandemic.