The premiere will benefit charities that support former and current members of Britain's intelligence agencies.

The Bond film franchise has a history with Britain's royal family. Over the years, many of them - including Princes William and Harry - have attended premieres and used the event to help support various charities.

More recently, 86-year old Queen Elizabeth made her film debut with James Bond star Daniel Craig during the opening ceremony of the 2012 London Olympics in July, in a spoof video that ended with her appearing to jump from a helicopter into the Olympic stadium.

"Skyfall," which stars Craig, Judi Dench, Javier Bardem, Ralph Fiennes, Naomie Harris and Albert Finney, will be released in the UK and internationally on Oct. 26. The film, directed by Sam Mendes, hits US theaters Nov. 9.