Reliance, which operates the world's biggest refining complex in western India, said net profit for its fourth quarter ended March 31 rose to 56.31 billion rupees from 55.89 billion rupees a year earlier.
Analysts on average expected a net profit of 56.62 billion rupees, according to Thomson Reuters I/B/E/S.
Average gross refining margin (GRM) dropped to $9.3 per barrel from $10.1 a year earlier.